Lopetegui signed three-year deal with Real Madrid on Monday.
Julen Lopetegui has been sacked as Spain boss.
It was announced on Tuesday the 51-year-old, who was in charge of the national team for two years, had agreed a three-year contract at Real Madrid to replace Zinedine Zidane.
At a press conference on Wednesday morning, it was announced Lopetegui would not take charge of the national side during the tournament in Russia.
Source: Sky Sports